- Open Access
- Total Downloads : 496
- Authors : Dr. S. Mohan, Dr. S. Palanivelraja, Dr. M. P. Chockalingam
- Paper ID : IJERTV3IS070496
- Volume & Issue : Volume 03, Issue 07 (July 2014)
- Published (First Online): 22-07-2014
- ISSN (Online) : 2278-0181
- Publisher Name : IJERT
- License: This work is licensed under a Creative Commons Attribution 4.0 International License
Environmental Impact Assessment with Respect to Ambient Air Quality in the Neighbourhood of a Typical Thermal Power Plant – A Case Study
1Dr. S. Mohan 2Dr. S. Palanivelraja, 3 Dr. M. P. Chockalingam,
Associate professor, Professor former Professor and Head, Deptofcivilengineering
,Faculty of Engineering&Technology Annamalai University-Chidambaram Tamilnadu,India-608002
ABSTRACT- A short term air quality survey was conducted for a period of about 20 days at Cuddalore , from 21.08.1987 to 10.09.1987, in the neighborhood of the proposed location of the Cuddalore Thermal power plant. Ambient air concentrations of the 3 major pollutants relevant to the Thermal power plant situation, namely, Sulphur Dioxide (SO2), Nitrogen Dioxide(NO2) and Suspended Particulate Matters (SPM) were measured on a continuous basis , in order to gather the baseline air quality data in the area . Nine sampling stations were operating at a time. The air concentrations of SO2, NO2, and SPM measured in the neighborhood of the proposed Cuddalore Thermal Power Plant site, during a 20-days experimental period in August- September 1987 were found to be well below the Ambient Air quality standard prescribed by the Government of India.
INTRODUCTION
There are number of problems associated with use of fossil fuel, such as pollution and green house effect [1, 2]. The issue of air pollution brought into attention in fourteen century, as combustion of coal caused air pollution [3]. Dispersion of carcinogenic chemicals reported to be as major source of pollution [4, 5]. Nowadays, the fossil fuel still is the major source of energy. Combustion of fossil fuel with sulfur content generates carbon monoxide, carbon dioxide, sulfur oxides and nitrogen oxides [3-6]. In order to reduce global air pollution, industrial zone outside of civilization and residential area were established. Green belt of forest around the civilized area for protection of the environment and reduction of air pollution were suggested [7-9]. The most important sources of fuel for energy conversion in thermal power plant are mainly fossil fuels, coal and natural gas [10-13]. Combustion of fuel generates gaseous products such as CO, SOx and NOx, which are considered major air pollutants. Most power plants using fossil fuel cause tremendous amount of environmental pollution. Elimination of pollution sources by using high quality of fuel would be able to reduce air pollution and to meet the international standards for clean environment [4-6, 14-18]. In industrialized countries, demand for electrical power is
rapidly developing. Along with massive power generation, tremendous amount of air pollution is also created. Therefore it is necessitate for assessing the impact of air quality on ambient environment
METHODOLOGY
High Volume Sampler (HVS) were used for the measurement of suspended particulate matter (SPM). Gravimetric method was employed for assessing the SPM concentration in ambient air.SO2 and NO2 were measured concurrently, employing a suitably designed bubblers technique similar to the Midget Impinger Assembly. West and Geake method was used for the analysis of SO2. Modified Jacob & Hochheiser (J-H) method was employed for analysis of NO2. The air concentration of SO2 and NO2were measured for an averaging time of 8 hours, continuously. SPM concentration were measured for an averaging time of 24 hours. The air sampling was done at the rate of 1.15 cubic meter per minute , through the HVS for the measurement of SPM, and at the 1.0 litre per minute through the midget impinge Assembly for the measurement of gaseous pollutants ,namely SO2 and NO2 .
Air Sampling Stations
Air sampling instrument were placed at 19 locations situated at various distance from the proposed power plant , in a such a way all the direction sector were represented. Most of the 19 sampling station were located on the 22.5 degrees direction-sector, with respect to the Power Plant Site. The distance between the sampling station and the power plant site varied between 2.7 kilometers and the 8.8 kilometers, thus ensuring immediate neighborhood of the power plant and the distant locations within a radius of 10.0 kilometers are represent in the air quality survey.
Nine sampling station were operating at the time in such a way that the entire land area around power plant site is represented , within 5.0 kilometer radius in the first
setting and within 10.0 kilometer radius in the second setting. Figure -1 represent the detail of the relative location of these sampling stations with represent to proposed power plant site and gives the details of distance and direction sector, for each station, with respect to the power plantsite
17
18
1
15
16
-
PACHCHANKUPPAM
19
9
-
THIAGAALLI
8
-
THIRUCHOPURAM
-
AGARAM
7
-
GODHANDARAMAPURAM
-
THONDAMANATHAM
6
14
-
SADAPALAYAM
5
13
-
ANNAVALLI
-
KARAIKADU
4
2
-
PERIYAPATTU
-
ANDARMULLIPALLAM
12
3
-
POOANIKUPPAM
-
ARUKKAMPATTU
-
AZHUKALAMPATTU
11
-
GANGAMANICHAMKUPPAM
-
AADIPALAYAM
10
-
CUDDALORE (NT)
-
CUDDALORE (OT)
PROPOSED SITE FOR CUDDALORE THERMAL POWER PLAN RAILWA LINE
HIGHWAY
Figure 1: location of the sampling stations with represent to proposed power plant site
RESULTS:
The summary of the baseline data of air quality prevailing in the neighborhood of the site proposed for the Cuddalore Thermal Power Plant is presented in table -1 indicating the maximum and the minimum of 8 hours SO2 concentration, 8-hour NO2 concentration and 24 hour SPM concentration as measured in all the 19 sampling station. The following trends are indicates in the base line data gathered during August September 1987
-
The maximum 8-hour SO2 concentration (21.0
µg/m3) was measured at station 10 ( Periyapattu village, located at about 8.8 kilometer south of the power plant site).
-
The maximum 8-hour NO2concentration (16.5
µg/m3) was measured at station 19 (neighborhood of Vanavil Dyes & Chemicals) located at about
3.6 kilometers North of the power plant site. This sampling station can be considered to represent the middle location of the SIPCOT Industrial Estates at Cuddalore
-
The maximum 24-hour SPM concentration (60.0
µg/m3) was measured at station 17 (cuddalore New Town ,Hotel Dwaraka location ) situated at about 8.0 kilometers North of the power plant site. The higher concentration of SPM (60.0 µg/m3) measured at this particular station ,in contrast to the other sampling station , can be remembered in the light of the fact that some construction work was in progress in the neighborhood during the period of air sampling.
-
the trend of the variation of individual readings of8-hour SO2, 8-hour NO2 and 24-hour SPM shown that the present air quality prevailing in the neighborhood of the proposed Cuddalore Thermal Power Plant site is in the compliance with the National Ambient Air Quality Standards prescribed by the Government Of India
-
The meteorological data available for the period of experimentation during August September 1987 indicates that the wind speed varied from calm ( no-wind) situation to a maximum of 7.22m/sec (26.0 kmph), the ambient air temperatue varied from 24.2 C to 37.4 C and the Relative Humidity varied from 42.0 percent to
100.0 percent, and the winds have been blowing from almost all directions-sectors (expecting the direction-sectors : North, North-North East, North-East and East).the prevalence of these wind directions would imply that the pollutants emitted from the industrial sources existing in the cuddalore SIPCOT Industrial Estate would have exerted an impact over the ambient air quality measured during the experimental period of 20 days in August September , 1987, as the sampling station were located all around, and
the baseline air quality measured in the area during this period could reflect the impact due to emission from the existing industrial source. Even under the influence of the existing industrial emissions, the background air quality presently prevailing in the cuddalore area seem to be in compliance with the ambient air Quality Standards prescribed by the Government of the India
Prediction of Future Air Quality
When the proposed 3*210 MW coal-fired power plant is commissioned at cuddalore , during stage-1 of the project, the emission rate will be 9.98X10*8 µg/sec of SO2,9.95X10*8 µg/sec of NO2, and 1.77 X 10*8 µg/sec of particulate matter ( assuming ESPS dust removal efficiency @ 99.5 percent).
Computer simulation modeling calculation indicate that the SO2 , NO2 and particulate matter emitted from the proposed 630 MW Thermal Power Plant at cuddalore would not exert any significant impact on the ambient air quality in the area around the power plant, considering downwind distances up-to 50.0 kilometers(please see Table-2). The physical stack height to be the provided for in the design is 275.0 meter which is in accordance with the recommendation of the Government of India , as per their revised guidelines.
In the Gaussian diffusion model employed in this study, for the purpose of prediction future air quality in cuddalore area, both long-term and short term meteorological data have been used .Mathematical modeling procedures have examined the worst air pollution situation that might arise under various combinations of atmospheric stability categories , wind speeds and other pertinent meteorological parameters. The possibilities of surface inversion occurrence and subsidence inversion occurrences have been considered, from the view point of air pollutant dispersion. Mean Mixing Depth were decided, depending upon the height at which the plume loses its ability to penetrate the cap of inversion, due to decreasing rate of buoyancy and momentum forces during its upward travel. In this approach, Mean Mixing Depth of 300.0 meter to 3000.0 meters have been considered while assessing the influence of mixing height over the dispersion of pollutants. Any mixing height less than the stack height (275.0 meters, in the present case) would be only help keeping the plume above the inversion layer, and the dispersion will be favorable.
Referring to Table -2, it can be seen that the maximum concentrations of pollutants would occur at a downwind location of 4.5 kilometers from the power plant, when a wind speed of 4.17 m/sec (15.0 kmph) prevails under the atmospheric stability class D ( neutral atmosphere), in which case , the maximum 1- hour SO2concentration would be 23.0 µg/m3, the maximum 1- hour NO2 concentration would be 22.9 µg/m3, and the 1- hour maximum SPM concentration would be 4.08 µg/m3. These 1-hour maximum concentration would correspond
to a maximum 8-hour concentration of 10.0 µg/m3 in the case of SO2, 9.8 µg/m3 in the case of NO2, and 24-hour maximum SPM concentration of 1.47 µg/m3 likely to occur at various sampling station chosen for the study , due to emissions from the initial units of 3*210 MW, on completion of stage -1.
Superimposing the estimated maximum concentration over the measured maximums, in respect of every sampling station, the future maximum concentrations likely to occur at these 19 locations , when
`the 3*210 MW units come into the operation , are shown in Table- 4, based on data show in Table-3 on the completion of stage-1 of the project, or in other word, when the initial electric generation capacity of 630 MW is achieved , the emission from the power plant might cause to occur a maximum 8-hour SO2 concentration of 28.8
µg/m3 , and a maximum 8-hour NO2 concentration of
-
µg/m3 at station 19. The estimated future maximum 24-hour SPM concentration of (61.0 µg/m3) would occur at station 17(Cuddalore New Town, Hotel Dwaraka location).These future maximum concentrations of SO2, NO2 and SPM would be individually well below the National Ambient Air Quality Standard prescribed by the Government of India.
CONCLUSIONS
-
The air concentrations of SO2, NO2, and SPM measured in the neighborhood of the proposed Cuddalore Thermal Power Plant site, during a 20-days experimental period in August- September 1987 were found to be well below the Ambient Air quality standard prescribed by the Government of India.
-
The results of a mathematical diffusion model, based on computer- aided simulation technique, indicate that the maximum estimated concentration of 8-hour SO2, 8-hour NO2, and 24 hour SPM when superimposed over the measured maximum of respective pollutants will be well below the prescribed Ambient Air Quality Standards, during all the stages of the Cuddalore Thermal Power Plant Project when the electric generation capacity reaches 630 MW.
-
50.0 45.0 40.0 35.0 30.0 25.0 20.0 15.0 10.0 5.0 0 5.0 10.0 15.0 20.0 25.0 30.0 35.0 40.0 45.0 50.0
3
50.0
45.0
40.0
SCALE:
X- Axis – 1.0 Cm = 2.0 Km
Y – Axis – 1.0 Cm= 2.0 ug / m
44
42
40
35.0
30.0
STAGEIII : 2050 MW : 5 X210 MW Plus 2 X500 MW
38
36
34
25.0
STAGEII : 1050 MW : 5 X210 MW
2
4 5 6
7 50.0
45.0
40.0
35.0
30.0
25.0
8 20.0
STAGEI : 630 MW : 3 X210 MW
20.0
32
30
28
26
24
22
20
18
16
14
12
10
8
6
4
2
(Estimated Maximum)
15.0
: COAL
FUEL USED SULPHUR CONTENT IN COAL
WIND SPEED
STABILITY CLASS STACK HEIGHT
10.0
: 0.55 %
: 4.17 m/sec
: D
: 275.0 m
5.0
1
3
0
0…5 ug///m 3
0…8 ug/// m3
1…0 ug /// m 3
3
0…09 ug /// m
0…09 ug/// m
3
3.0 ug / m
5.0 ug / m
33
15.0
10.0
5.0
9
0
SO 2CONC. ug / m
5.0
10.0
15.0
16
20.0
25.0
1…0 ug /// m
3
3
0…8 ug/// m
3
0.8 ug / m
3
0…5 ug/// m 3
5.0
10.0
15.0
20.0
10 25.0
3
30.0
1.0.0 ug / m
30.0
35.0
2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 40 42 44 46 48 50
40.0
FIGURE- ESTIMATED MAXIMUM DOWNWIND 8 – HOURS CONCENTRATION; O2F SO DURING STAGES – I, II &III
45.0
50.0 15
14 13
0..5.5 ug //m>
12 11
35.0
40.0
45.0
50.0
50.0 45.0 40.0 35.0 30.0 25.0 20.0 15.0 10.0 5.0
0 5.0 10.0 15.0 20.0 25.0 30.0 35.0 40.0 45.0 50.0
FIGURE 2: Estimated Maximum downwind 8-Hours Concentration of SO
FIGURE 3: POLLUTION ROSE FOR NO2
50.0
45.0
40.0
35.0
30.0
25.0
20.0
15.0
10.0
5.0
0
5.0
10.0
15.0
20.0
25.0
30.0
35.0
40.0
45.0
50.0
50.0 45.0 40.0 35.0 30.0 25.0 20.0 15.0 10.0 5.0 0 5.0 10.0 15.0 20.0 25.0 30.0 35.0 40.0 45.0 50.0
111555
111666
111
222
3
444
111444
111333
5
111222
666
111111
111000
999
888
7
LEGEND
1 16 SIXTEEPOINT DIRECTION – SECTORS
PROPOSED POWER SITE
333
0.09 ug/m
33
0.02 ug/m3
0.9 ug/m3
0.5 ug/m3
0.2 ug/m
0.2 ug/m
333
333
333
0.09 ug/m
0.1 ug/m
0.02 ug/m3
3
0.1 ug/m
333
333
00..1 ugg///m
00..09 ugg///m
AirSampling StationNo.& Name |
8 Hrs. Conc. SO2 (µg/m3) |
8 Hrs. Conc. NO2 (µg/m3) |
8 Hrs. Conc. SPM (µg/m3) |
|||
Ma x. |
Min . |
Ma x. |
Min . |
Ma x. |
Min . |
|
1.Pachahankuppa m |
10.0 |
0.6 |
7.3 |
0.5 |
37.9 |
24.0 |
2.Thiagavalli |
13.9 |
4.5 |
11.0 |
1.1 |
29.3 |
16.8 |
3.Thiruchopuram |
12.7 |
4.9 |
9.6 |
2.9 |
32.1 |
20.4 |
4.Agaram |
12.4 |
1.8 |
9.8 |
1.0 |
33.3 |
20.4 |
5.Gadhandaramap uram |
15.7 |
2.3 |
7.0 |
0.8 |
37.2 |
24.3 |
6.Thandamanatha m |
14.2 |
2.2 |
7.5 |
1.5 |
31.3 |
19.7 |
7.Sedapalayam |
14.1 |
7.9 |
7.2 |
4.1 |
35.5 |
23.7 |
8.Annavalli |
15.8 |
1.2 |
9.7 |
0.9 |
32.4 |
21. |
9.Karaikadu |
18.6 |
1.6 |
9.2 |
0.7 |
34.3 |
21.7 |
10.Periyapattu |
21.0 |
7.6 |
9.7 |
5.2 |
28.2 |
18.1 |
11.Andarmullipall am |
14.4 |
7.1 |
9.2 |
2.7 |
32.9 |
25.5 |
12.Poovanikuppa m |
18.3 |
7.7 |
9.1 |
3.2 |
29.5 |
19.7 |
13.Arukkampattu |
17.2 |
6.3 |
9.1 |
3.2 |
27.7 |
18.7 |
14.Vazhukalampat tu |
16.7 |
7.6 |
11.2 |
3.2 |
27.7 |
18.7 |
15.Gangamanicha mkuppam |
14.9 |
5.6 |
13.3 |
3.1 |
34.1 |
21.3 |
16.Navadipalayam |
13.2 |
503 |
8.1 |
2.0 |
37.0 |
20.3 |
17.Cuddalore New Town(Hotel Dwaraka) |
14.5 |
3.8 |
9.1 |
1.8 |
60.0 |
30.3 |
18.Cuddalore Old Town (ADEs office) |
14.9 |
4.3 |
9.8 |
1.2 |
48.1 |
32.1 |
19.Vanavil Dyes & Chemicals |
20.0 |
9.1 |
16.5 |
4.8 |
34.5 |
26.5 |
50.0 45.0 40.0 35.0 30.0 25.0 20.0 15.0 10.0 5.0 0 5.0 10.0 15.0 20.0 25.0 30.0 35.0 40.0 45.0 50.0
50.0
45.0
40.0
35.0
30.0
25.0
20.0
15.0
10.0
5.0
0
5.0
10.0
15.0
20.0
25.0
30.0
35.0
40.0
45.0
50.0
TABLE :1
TREND OF AMBIENT AIR QUALITY VARIATIONS AT CUDDALORE
DURING AUGUST SEPTEMBER 1987
Distance (Km)
Distance (Km)
FIGURE: POLLUTION ROSE FOR SPM
Note: the maximum and minimum concentrations of pollutants are shown underlined
FIGURE 4: POLLUTION ROSE FOR NO2
TABLE: 2
Estimated Maximum Ground level concentrations of Pollutants at various
Downwind Locations, for 3 units of 210 MW each: (Stage I)
Stack Height : 275.0
Mixing Depth : 500.0m No. of Stacks : 1
Sulphur : 0.475%
TABLE :3
ESTIMATED MAXIMUM POLLUTANT CONCENTRATIONS LIKELY TO OCCUR IN CUDDALORE AREA, DUE TO POWER PLANT EMISSIONS: STAGE I
Source : 3 x210 MW
Coal Fired Units
No.of Stacks : 1
Stack Height :275.0Meters
Sulphur : 0.475&
Sta bilit y Cla ss |
µ (m/sec ) |
x (km) |
SO2 Conc. (µ/m3) |
NO2 Conc. (µ/m3) |
SPM Conc. (µ/m3) |
|||
1 Hr. |
8 Hr. |
1 Hr. |
8 Hr. |
1 Hr. |
8 Hr. |
|||
(1) |
(2) |
(3) |
(4) |
(5) |
(6) |
|||
A |
0.25 |
25.0 |
0.0 3 |
0.0 1 |
0.0 3 |
0.0 1 |
0.0 05 |
0.0 02 |
A-B |
0.25 |
35.0 |
0.0 7 |
0.0 3 |
0.0 7 |
0.0 3 |
0.0 1 |
0.0 04 |
B |
0.25 |
45.0 |
0.1 7 |
0.0 8 |
0.1 7 |
0.0 8 |
0.0 3 |
0.0 1 |
A |
1.00 |
1.0 |
1.2 |
0.5 |
1.2 |
0.5 |
0.2 1 |
0.0 8 |
A-B |
1.00 |
6.0 |
1.6 |
0.7 |
1.6 |
0.7 |
0.2 8 |
0.1 0 |
B |
1.00 |
7.0 |
1.6 |
0.7 |
1.6 |
0.7 |
0.2 8 |
0.1 0 |
A |
1.75 |
2.5 |
2.8 |
1.2 |
2.8 |
1.2 |
0.5 0 |
0.1 8 |
A-B |
1.75 |
3.0 |
2.5 |
0.9 |
2.5 |
0.9 |
0.4 4 |
0.1 6 |
B |
1.75 |
3.0 |
4.5 |
2.0 |
4.5 |
2.0 |
0.8 0 |
0.2 9 |
A-B |
3.00 |
1.5 |
4.4 |
1.9 |
4.4 |
1.9 |
0.7 8 |
0.2 8 |
B |
3.00 |
2.0 |
8.1 |
3.5 |
8.1 |
3.5 |
1.4 3 |
0.5 2 |
C |
3.00 |
2.5 |
12. 9 |
5.6 |
12. 9 |
5.6 |
2.2 8 |
0.8 2 |
E |
3.00 |
9.0 |
21. 0 |
9.1 |
20. 9 |
9.1 |
3.7 2 |
1.3 4 |
F |
3.00 |
14.0 |
19. 3 |
8.5 |
19. 2 |
8.4 |
3.4 2 |
1.2 3 |
D |
4.17 |
4.5 |
23 |
10 |
22. 9 |
9.8 |
4.0 8 |
1.4 7 |
Sampling Station |
SO2 Conc. (µ/m3) |
NO2 Conc. (µ/m3) |
SPM Conc. (µ/m3) |
8 Hrs. |
8 Hrs. |
24 |
|
1.Pachahankuppam |
9.7 |
9.6 |
1.4 |
2.Thiagavalli |
4.7 |
4.3 |
0.7 |
3.Thiruchopuram |
9.6 |
9.6 |
1.4 |
4.Agaram |
10.0 |
9.4 |
1.5 |
5.Gadhandaramapura m |
9.1 |
9.0 |
1.3 |
6.Thandamanatham |
9.4 |
9.4 |
1.4 |
7.Sedapalayam |
7.4 |
7.4 |
1.1 |
8.Annavalli |
8.8 |
8.8 |
1.3 |
9.Karaikadu |
9.2 |
9.2 |
1.4 |
10.Periyapattu |
5.6 |
5.6 |
0.8 |
11.Andarmullipallam |
6.6 |
6.6 |
0.9 |
12.Poovanikuppam |
7.8 |
7.7 |
1.1 |
13.Arukkampattu |
8.7 |
8.6 |
1.3 |
14.Vazhukalampattu |
6.1 |
6.1 |
0.9 |
15Gangamanichamku ppam |
6.6 |
5.6 |
1.0 |
15.Navadipalayam |
6.4 |
6.3 |
0.9 |
16.Cuddalore New Town(Hotel Dwaraka) |
6.4 |
6.4 |
0.9 |
17.CuddaloreOld Town (ADEs office) |
8.7 |
8.6 |
1.3 |
18.Vanavil Dyes & Chemicals |
8.8 |
8.8 |
1.3 |
TABLE :4
FUTURE MAXIMUM CONCENTRATIONS OF POLLUTANTS LIKELY TO OCCUR IN VARIOS DOWNWIND LOCATIONS, ON THE COMPLETION OF STAGE I OF THE PROJECT: 3 X 210 MW
(Estimated Maximums Superimposed over the measured Maximums)
Sulphur : 0.475%
Sampling Station |
SO2 Conc. (µ/m3 ) 8 Hrs. |
NO2 Conc. (µ/m3 ) 8 Hrs. |
SPM Conc. (µ/m3) 12 Hrs. |
REMARK S |
1.Pachahankuppam |
19.7 |
16.9 |
39.3 |
|
2.Thiagavalli |
18.6 |
15.3 |
30.0 |
|
3.Thiruchopuram |
22.3 |
19.2 |
33.5 |
|
4.Agaram |
22.4 |
19.2 |
34.8 |
|
5.Gadhandaramapura m |
24.8 |
16.0 |
38.5 |
|
6.Thandamanatham |
23.6 |
16.8 |
26.9 |
|
7.Sedapalayam |
21.5 |
14.6 |
36.6 |
|
8.Annavalli |
24.6 |
18.5 |
37.9 |
|
9.Karaikadu |
27.8 |
18.4 |
35.7 |
|
10.Periyapattu |
26.6 |
15.3 |
29.0 |
|
11.Andarmullipallam |
21.0 |
15.8 |
33.9 |
|
12.Poovanikuppam |
26.1 |
16.8 |
30.6 |
|
13.Arukkampattu |
25.9 |
17.7 |
31.4 |
|
14.Vazhukalampattu |
22.8 |
17.3 |
28.6 |
|
15.Gangamanichamku ppam |
21.5 |
19.8 |
35.1 |
|
16.Navadipalayam |
19.6 |
14.4 |
37.9 |
|
17.Cuddalore New Town (Hotel Dwaraka) |
20.9 |
15.5 |
61.0 |
Maximum SPM |
18.Cuddalore Old Town (ADEs office) |
23.6 |
18.4 |
49.4 |
|
19.Vanavil Dyes & Chemicals |
28.8 |
25.3 |
35.8 |
Maximum SO2& NO2 |
REFERENCES:
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