Passive Cooling of Building using Glycerine and Paraffin Wax with Perlite as Phase Changing Materials

Passive Cooling of Building using Glycerine and Paraffin Wax with Perlite as Phase Changing Materials

Dr. P. Kathirvel, Dr. R. Lakshmi

Professor / Civil Engineering

Kamaraj College of Engineering and Technology Madurai 625701, India.

1. Ahamed Ibrahimsha, A. Gowri Sankar,

   1. Karthick Siva, P. S. Poorna Prakash

      Former UG Students

      Kamaraj College of Engineering and Technology Madurai 625701, India.

      Abstract The exponential increase in population growth has led to increase in high consumption of natural resources, which directly and indirectly is the source of liberation of CO2 in the atmosphere. Along with the construction industry, which is also a major source of liberation of greenhouse gases, active cooling devices such as the air conditioners & refrigerators also become the major source of emission of greenhouse gases. In order to control the room temperature by passive method, Phase Changing Materials (PCM) can be used in buildings. PCMs or latent heat storage materials are generally materials with large specific latent heat capacity. PCMs used in buildings will typically melt and solidify within a range of 18-30oC and are normally integrated in the building fabric. They can be used in the built environment to reduce internal temperature change by storing latent heat in the solid-liquid or liquid-gas phase change of a material. PCMs are found to store 5 to 14 times more thermal energy per unit volume than conventional thermal storage materials. The main objective of this project is to obtain ambient temperature within buildings and to reduce the usage of the active cooling machineries which releases greenhouse gases responsible for earths temperature rise. Telkes and Tyaghiare the first researchers, who have undertaken the work on application of PCMs in buildings in 1975 and concluded that they can be incorporated with ordinary building materials. Organic PCMs like Paraffin wax and Glycerine are used and infiltrated with cement mortar. To prevent the leakage of these PCMs Perlite is used. The objective of the present work is to study the effects of various types of PCM including Glycerine, Paraffin wax and Perlite with Paraffin wax in control of the room temperature from mortar plastered brick masonry model and comparing the results by simulating in software.

      KeywordsPhase change materials; passive cooling in building; paraffin wax; glycerine; perlite

      1. INTRODUCTION

         The major causes of global warming are by Carbon di- oxide (CO2) which is an important greenhouse gas released through human actions such as burning fossil fuels and deforestation, as well as natural processes such as respiration and upsurge of volcanoes. It is expected that an increase of

         +1C of room temperature In years. PCM is a material with a high heat of fusion which, melting and solidifying at a certain temperature, is capable of storing and discharging large quantities of energy. When the outside temperature is more than ambient temperature, the PCM changes to liquid phase and prevents the entry of heat inside. When the outside temperature is less than ambient temperature, the PCM

         changes to solid phase and prevents the entry of heat inside. The Phase change materials are basically classified into two types, namely Organic PCM and Inorganic PCM. The organic PCMs are naturally available materials such as Lauric acid, Paraffin Carbons, Formic acid, Glycerine, which are safe, stable, freeze at lesser drop in temperature and are recyclable. However they have low thermal conductivity in their solid state and are most costly. The Inorganic PCMs such as Sodium sulphate, sodium chloride, Aluminium, Gold, Copper, Silver, Titanium, etc. are chemicals which have high volumetric latent heat storage capacity, sharp melting point, high thermal conductivity and are relatively low cost. However their change of volume is very high and often become defective after in due course.

         The study of A.Yahaya et.al. (2011) showed that the application of PCM slab panels could effectively reduce the energy consumption through active cooling systems. Application of PCM wallboards in building delivers latent heat storage throughout the building envelope (Arash Bastani et.al, 2015). The incorporation of a PCM layer into an external building wall reduced the magnitude of the sudden heat flux through the wall (Necib Hichemet.al, 2013). An evaluation of a brick with and without PCM showed a temperature difference of 3.78°C. Concrete prepared with 10%, 15%, and 20% of paraffin wax which has melting point 26, showed upto 20% much lower temperature than the blank sample. The temperature difference value is about 3.6oC in heating condition and is about 2.4oC in cooling condition (Qing Wang et.al, 2012). Perlite, diatomite, expanded graphite, and silica fume are commonly used with PCM to prevent leakage and to attain the required strength (Huiqiang Li et.al,2014). Highest Compressive Strength was obtained while mixing the Paraffin wax and the hydrophobic fumed silica in Cement Mortar where leakage of paraffin can be prevented by adding hydrophobic fumed silica, PCMs may increase the thermal mass of lightweight buildings and then equalize the indoor temperature swings by which peak load flowing could be achieved (Guobing Zhou, et.al, 2011). The simulations, carried out in PCM wallboards, showed a potential reduction of 2oC in the peak indoor air temperature (G. Evola, et.al, 2013). The heat flux at the indoor space can be reduced by 17.55% when three PCM cylinders are introduced placed at the centre line of bricks (Esam M.

         Alawadhi, et.al, 2008). PCM in conventional and alveolar brick construction reduced the energy consumption compared with the same cubicle without PCM (A. Castell, et.al, 2010).

         The use of PCM in brick walls is helpful for the thermal insulation, temperature hysteresis and thermal comfort for occupants (Chengbin Zhang, et.al, 2011). Compared to a brick wall, Gypsum board with 45% PCMs stores five times more energy per unit mass, 9.5 times more energy and about three times more energy per unit mass than a ordinary gypsum board (Alicia Oliver et.al, 2012). The thermal amplitude is decreased in the interior domain with the increase of the PCM thickness. The model with the larger PCM thickness of 25 mm reduces about 22% (Tiago Silva, et.al, 2012). PCM used is able to absorb the heat developing from the external thermal conditions, thereby changing its phase from solid to liquid. During the night time the PCM solidifies and releases the stored heat. The application of PCM led to a delay of about six hours in the heat flux peak, and a reduction of 25% (Paolo Principi, et.al, 2012). A thermal analysis of a building concrete roof with vertical cylindrical holes filled with PCM showed that the heat flux at the indoor surface of the roof can be reduced between 12.04% and 17.26% depending on the operating month (Hashem.J.Alqallaf, et.al, 2013). PCM in perforated brick rooms produced result with good effect of decreasing temperature peak (1oC to 2.3oC), reducing temperature fluctuation and increasing the thermal inertia, and indicated the opportunity of PCM panel usage (Xiangfei Kong, Shilei Lu, et.al, 2013). The use of silver nanoparticles in PCM Paraffin wax enhances the ability of thermal energy storage of the materials. (Pradeep.N.et.al, 2020). From the review of literature, the most widely used PCM is Paraffin wax. PCMs have a better temperature control while adding in cement mortar and plastering. Perlite prevents the leakage of PCM during exposing condition. Other PCMs (such as Glycerine) can also be used in effective temperature control.

      2. MATERIALS AND METHODS

         1. Material Collection and Model Preparation

            Four numbers of brick masonry room models were prepared (Fig.1(a),(b),(c)) with inner size 600mm x 600mm x 600mm, covered by Reinforced Cement Concrete (RCC) slab of size 600mm x 600mm x 75mm M20 grade concrete with reinforcement 6mm @ 150mm c/c both ways. The walls were make of red brick 150mm thick with mortar and plastering by Cement Mortar (CM) 1:5 mix. A small opening of size 150mm x 150mm was provided on one wall to enable the study of temperature inside the room at regular intervals.

            Fig.1 (a) Cover slab; (b) Prototype brick work; (c) Prototype wall plastered

            The variation in the four models were the PCMs used in the cement mortar used between the bricks, inner and outer wall plaster. The PCMs used in the three models were 5% Glycerine, 5% Paraffin wax and 5% Paraffin wax with Perlite,

            the results of which were compared with the control mix of only cement mortar used. The four mixes are given in Table 1.

            TABLE 1 Mix Proportions

            S.No.	Mix ID	Cement Mortar	PCM (by weight of Cement)
            1	CM	1 : 5	–
            2	CMG	1 : 5	5% Glycerine
            3	CMP	1 : 5	5% Paraffin Wax
            4	CMPP	1 : 5	5%Paraffin Wax+5% Perlite

            The temperature variation in the four prototype models were studied for 30 days during morning, afternoon and evening. The temperature readings were taken through using industrial temperature sensor for 12 hours per day. Also to find the thermal variation in the prototype ANSYS modelling software was used to model the thermal variation of the four models with the same materials and dimensions and plotted to get the 2D Thermal Variation of Brick, as shown in Fig.2.

            Fig.2 Two Dimensional Pattern of Wall brick done using ANSYS software

         2. Physical properties Test

         The specific gravity of the raw materials including cement, fine aggregate and coarse aggregate were found as per standards, as 3.15, 2.65 and 2.65 respectively. The four mix proportions of cement mortar were tested for water absorption. The compressive strength of the mortar mixes were arrived as per IS 4031-1988(Part 6). To find the coefficient of thermal conductivity of a cement mortar with different proportions using Lees Disc Apparatus. The thermal conductivity was calculated by using Equation 1.

         K= (*(+)*(/)*/*(-)*(+)) //k (1)

         where, M- Mass of the metal disc in kg

         s Specific heat capacity of the material of disc in Jkg-1K-1 d Thickness of a bad conductor in m

         r Radius of the metallic disc in m h Thickness of the metal disc in m

         1 – steady state temperature of the steam chamber oC

         – steady state temperature of the metal disc in

         oC / rate of cooling at steady state temperature

      3. RESULTS AND DISCUSSION

         The results of the compressive strength test, thermal conductivity test for the four mixes in the models have been tabulated below.

         1. Compressive Strength Test

            The compressive strength of the mixes added with PCM showed lesser results than the control mortar mix CM. However the strength of mortar in brick and plastering is immaterial when the brick walls are used in framed buildings and non-load bearing walls.

            TABLE 2 Compressive Strength Test

            S. No.	Mix ID	Compressive Strength (N/mm2)
            1	CM	9.61
            2	CMG	3.98
            3	CMP	3.71
            4	CMPP	4.50

         2. Water Absorption Test

         The water absorption test from Table 3 also showed results similar to the compressive strength test where the absorption increased for the mortar mixes with PCMs but were within the limits.

         E. Temperature variation of outside, CM and CMP mixes

         The Fig.4 shows the average temperature between outside temperature and CM without PCM and CMP. The CMP was found to give reduction in temperature of 2% during day time and increase in temperature of 2% during night time.

         S. No.	Mix ID	Water Absorption (%)
         1	CM	1.23
         2	CMG	1.29
         3	CMP	2.70
         4	CMPP	2.78

         S. No.	Mix ID	Water Absorption (%)
         1	CM	1.23
         2	CMG	1.29
         3	CMP	2.70
         4	CMPP	2.78

         TABLE 3 Water Absorption Test

         1. Thermal Conductivity Test (Lees Disc Apparatus)

            Table 4 shows the results of the thermal conductivity value, in this CMPP shows the lowest value of all others. High thermal conductivity are generally used in heat drop applications and the materials of low thermal conductivity are used as thermal insulation.

            TABLE 4 Thermal Conductivity Test

            S. No.	Mix ID	Thermal Conductivity (W/m/k)
            1	CM	0.52
            2	CMG	0.68
            3	CMP	0.44
            4	CMPP	0.39

         2. Temperature variation of outside, CM and CMG mixes

         The variation of temperatures is shown in a graph for respective 12 hours timely readings. The Fig.3 shows the average temperature between outside temperature and CM without PCM and CMG. The CMG was found to give the better results with reduction in temperature of 3% during day time and increase in temperature of 3% during night time.

         Fig.3 Temperature variation of outside, CM and CMG mixes

         Fig.4 Temperature variation of outside, CM and CMP mixes

         1. Temperature variation of outside, CM and CMPP mixes

            Fig.5 shows the average temperature between Outside temperature, CM without PCM and CMPP. The CMPP was found to give the better results with reduction in temperature of 5% during day time and increase in temperature of 5% during night time.

            Fig.5 Temperature variation of outside, CM and CMPP mixes

         2. Thermal variation from ANSYS of CM with PCMs for four mixes at 9am

            To find the temperature reduction in each of the Model wall bricks from Outside Surface to Inner Surface a two dimensional analysis of brick with CM and PCM were modelled and analyzed using ANSYS software. These kinds of analysis were done and visualized the heat flux with all mixed proportions. Fig.6 shows the thermal conductivity results outside and inside the wall at 9am for the four mixes. It is seen from the graph that CMPP shows the best thermal insulation.

            Fig.6 Thermal variation from ANSYS of CM with PCMs for four mixes at 9am

         3. Thermal variation from ANSYS of CM with PCMs for four mixes at 12 noon.

            Fig.7 shows the thermal variation analysed by Ansys software for 12 pm. In this the forth composition with paraffin and perlite shows the best thermal insulation for 12 pm.

            Fig.7 Thermal variation from ANSYS of CM with PCMs for four mixes at 12 noon

         4. Thermal variation from ANSYSof CM with PCMs for four mixes at 3pm

            Fig.8 shows the thermal variation analysed by Ansys software for 3 pm. In this the forth composition with paraffin and perlite shows the best thermal insulation for 3 pm.

            Fig.8 Thermal variation from ANSYS of CM with PCMs for four mixes at 3pm

         5. Thermal variation from ANSYS of CM with PCMs for four mixes at 6pm

            Fig.9 shows the thermal variation analysed by Ansys software for 6 pm. In this the forth composition with paraffin and perlite shows the best in maintaining the ambient temperature during very cold period for 6 pm.

            Fig.9 Thermal variation from ANSYS of CM with PCMs for four mixes at 6pm

         6. Thermal variation from ANSYS of CM with PCMs for four mixes at 9pm

         The above graph shows the thermal variation analysed by Ansys software for 9 pm. In this the forth composition with paraffin and perlite shows the best in maintaining the ambient temperature during very cold period for 9 pm.

         Fig.10 Thermal variation from ANSYS of CM with PCMs for four mixes at 9pm

      4. CONCLUSION

The three PCM mixes proved to perform well in regulating the temperature within the prototype building. The CMPP mix with 5% paraffin and 5% perlite was found to control the temperature by 5% both during day and night, which can be effectively used as a passive air conditioning method in buildings. Though the strength of the mortar mix reduces compared to the control mix, it does not have impact on the brick masonry walls owing to the usage of non-load bearing walls in framed structures, which are the most adopted method of construction these days.

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